The only thing stopping a reorganization of PCS+AWS to DCS+IMT is the 1755-1850 MHz still currently in use by the government. Once that paired AWS-3 spectrum (1755-1780 MHz, 2155-2180 MHz) is freed up, it would become possible to reband to IMT, but not DCS without more spectrum freed up.
IMT uses 1920-1980 MHz for uplink (UL) and 2110-2170 MHz for downlink (DL).
PCS (A-F) uses 1850-1910 MHz for UL and 1930-1990 MHz for DL. G block adds 5 MHz to UL and 5 MHz to DL. H block adds another 5 MHz to UL and another 5 MHz to DL.
DCS uses 1710-1785 MHz for UL and 1805-1880 MHz for DL.
AWS uses 1710-1755 MHz for UL and 2110-2155 MHz for DL. Paired AWS-3 adds 25 MHz to UL and 25 MHz to DL.
With the AWS-3, PCS G, and PCS H frequencies released, the following frequency ranges would be available: 1710-1780 MHz, 1850-1920 MHz, 1930-2000 MHz, 2110-2180 MHz.
Rebanding would permit a partial IMT allocation: 1930-1980 MHz for UL, and 2120-2170 MHz for DL. If the PCS duplex gap frequencies can be allocated (1920-1930 MHz), then a full IMT allocation is possible.
DCS would still not be doable. The 1805-1850 MHz under DCS is allocated to the federal government for research and military use at this time. On the other hand, the reorganization could allow the government to shift federal use to previously occupied frequencies for PCS to enable DCS. But this would be quite challenging. I'd say it would require 10-15 years of work to do it.
Efforts are better spent fixing bands that have frequencies already allocated. 2.6GHz and 700MHz are better deserving the effort to fix them than PCS and AWS. Besides, PCS and AWS have large ecosystems in their own right. US 700MHz does not, nor does Band 41 2.6GHz.
Impossible. Bands 13+14 have an reversed duplex configuration from Band 12. That means that not even a cascading duplexing scheme would work, as the relative positioning of the downlink and uplink channels is flipped for half the band. There was little to no planning actually done in the development of the 700MHz band plan, which is why it isn't that efficient and does not promote the development of a large ecosystem.
However, there is no reason a device can't support bands 12, 13, and 14 separately in one device. Meaning, that there would be a duplex path for band 12 (with subset 17 supported), and a duplex path for bands 13+14.